By 前田 富祺, 野村 雅昭
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Diaphragm Cells Description. 6 A permeable diaphragm separates the cell into two compartments. 2. Schematic of a diaphragm cell. 9 ELECTROLYTIC CELL DEVELOPMENT the cell in the anode compartment, ﬂows through the diaphragm, and exits the cell from the cathode compartment. Chlorine gas is formed at the anode, and hydrogen gas is formed at the anode. Both of these gases are vented from the cell and processed elsewhere in the plant. The liquid discharged from the cathode compartment is a mixture of diluted brine and dilute sodium hydroxide.
The cell membranes are highly sensitive to calcium deposits, and if this limit is not achieved, process performance will suffer and maintenance costs will escalate. Hydrochloric acid is added to the brine to neutralize part of the back migration of hydroxide ions. These ions reduce the formation of objectionable byproducts before the puriﬁed brine is fed to the anode compartments of the cells. The salt is electrically decomposed to produce the chlorine gas generated at the anode. The sodium ions remain in solution and are transported through the membrane to the cathode, where they combine with hydroxide ions formed in the cathode chamber.
Black & Veatch, Chapter 1 Roger D. , Black & Veatch, Chapter 15 Gary W. , Black & Veatch, Chapter 10 Kerwin L. , Chapter 15 xxxi xxxii LIST OF CONTRIBUTORS AND REVIEWERS Stephen J. , University of Kansas, Chapter 4 Don D. Ratnayaka, CEng, Black & Veatch, Chapters 4 and 14 Andrew R. , Black & Veatch, Chapter 2 Edward D. , Chapter 17 Timothy J. ) ion chromatography Information Collection Rule immediate danger to life and health Interim Enhanced Surface Water Treatment Rule International Fire Code Institute ion exchange Lead and Copper Rule liquid oxygen lower sensitivity limit Long-term 1 Enhanced Surface Water Treatment Rule Long term 2 Enhanced Surface Water Treatment Rule Manufacturing Chemists Association maximum contaminant level maximum contaminant level goal method detection limit microﬁltration modiﬁed fouling index 2-methylisoborneol mixed liquor volatile suspended solids most probable number maximum residual disinfectant level goal material safety data sheets minimum water column maximum water depth; Metropolitan Water District; minimum water depth N-nitrosodimethylamine nanoﬁltration National Fire Protection Association nominal molecular weight nitrite-oxidizing bacteria natural organic matter National Pollutant Discharge Elimination System National Sanitation Foundation National Transportation Safety Board oxidation-reduction potential Occupational Safety and Health Administration orthotolidine orthotolidine-arsenite powdered activated carbon phenylarsine oxide programmable controller polychlorinated biphenyl process control software xxxvi PDWF PFU PICS PLC PPCP PSA PSM PSS PSU PTFE PVC RAA RAS RCP RMP RMPP RO RSI RTK RTU SCF SDH SDI SDWA SETIQ SFPC SHMP SLS SMCL SOC SPC SS STEL SW SWTR TC TCA TCE TCEP TDD TDH TDS TFC THM LIST OF ABBREVIATIONS peak dry weather ﬂow plaque-forming unit process instrument control system programmable logic controller pharmaceutical and personal care product pressure swing adsorption process safety management point summation source power supply unit polytetraﬂuoroethylene polyvinyl chloride running annual average return activated sludge reinforced concrete pipe risk management program risk management protection plan reverse osmosis Railway Supply Institute right-to-know remote terminal unit short circuiting factor succinic dehydrogenase silt density index Safe Drinking Water Act Sistema de Emergencies en Transporte para la Industria Quimica Standard Fire Prevention Association sodium hexametaphosphate sodium lauryl sulfate secondary maximum contaminant levels synthetic organic compound standard plate count suspended solids short-term exposure limit spiral wound Surface Water Treatment Rule total coliform trichloroacetic acid trichloroethylene tris (2-chloroetlyl) phosphate triple distilled deionized total dehydrogenase; total dynamic head total dissolved solids thin-ﬁlm composite trihalomethanes LIST OF ABBREVIATIONS THMFP TLV TOC TON TOX TRANSSCAER TRC TSS TTCE TTHM TWA UBC UF UFC UP USEPA USGS UV UVA VOC VSA WEF WPCF WTP WWTP xxxvii trihalomethane formation potential threshold limit value total organic carbon threshold odor number total organic halides Transportation Community Awareness and Emergency Response total residual chlorine total suspended solids tetrachloroethylene total trihalomethane time weighted average Uniform Building Code ultraﬁltration Uniform Fire Code Union Paciﬁc United States Environmental Protection Agency (also EPA) United States Geological Service ultraviolet ultraviolet absorbance at 254 nm volatile organic carbon/compound vacuum swing adsorption Water Environment Federation Water Pollution Control Federation water treatment plant wastewater treatment plant ACKNOWLEDGMENTS We give special thanks to Alan Ingham and Dan Wright for assistance with graphic arts.